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  1. Mantaray: A Rust Package for Ray Tracing Ocean Surface Gravity Waves

    Ocean surface gravity waves are an important component of air-sea interaction, influencing energy, momentum, and gas exchanges across the ocean-atmosphere interface. In specific applications such as refraction by ocean currents or bathymetry, ray tracing provides a computationally efficient way to gain insight into wave propagation. In this paper, we introduce Mantaray, an open-source software package implemented in Rust, with a Python interface, that solves the ray equations for ocean surface gravity waves. Mantaray is designed for performance, robustness, and ease of use. The package is modular to facilitate further development and can currently be applied to both idealized and realisticmore » wave propagation problems (Fig. 1).« less
  2. Observed declines in upper ocean phosphate-to-nitrate availability

    Climate warming is increasing ocean stratification, which in turn should decrease the nutrient flux to the upper ocean. This may slow marine primary productivity, causing cascading effects throughout food webs. However, observing changes in upper ocean nutrients is challenging because surface concentrations are often below detection limits. We show that the nutricline depth, where nutrient concentrations reach well-detected levels, is tied to productivity and upper ocean nutrient availability. Next, we quantify nutricline depths from a global database of observed vertical nitrate and phosphate profiles to assess contemporary trends in global nutrient availability (1972–2022). We find strong evidence that the P-nutriclinemore » (phosphacline) is mostly deepening, especially throughout the southern hemisphere, but the N-nutricline (nitracline) remains mostly stable. Earth System Model (ESM) simulations support the hypothesis that reduced iron stress and increased nitrogen fixation buffer the nitracline, but not phosphacline, against increasing stratification. These contemporary trends are expected to continue in the coming decades, leading to increasing phosphorus but not nitrogen stress for marine phytoplankton, with important ramifications for ocean biogeochemistry and food web dynamics.« less
  3. Sensitivities of the West Greenland Current to Greenland Ice Sheet Meltwater in a Mesoscale Ocean/Sea Ice Model

    Abstract Meltwater from the Greenland Ice Sheet can alter the continental shelf/slope circulation and cross-shelf freshwater fluxes and limit deep convection in adjacent basins through surface freshening. We explore the impacts on the West Greenland Current and eastern Labrador Sea with different vertical distributions of the meltwater forcing. In this study, we present the results from global coupled ocean/sea ice simulations, forced with atmospheric reanalysis, that are mesoscale eddy-active (∼2–3-km horizontal spacing) and eddy-permitting (∼6–7-km horizontal spacing) in the study region. We compare the West Greenland Current in mesoscale eddy-active and eddy-permitting without meltwater to highlight the role of small-scalemore » features. The mesoscale eddy-active configuration is then used to assess the change in the eastern Labrador Sea when meltwater is added to the surface or vertically distributed to account for mixing within fjords. In both simulations with meltwater, the West Greenland and West Greenland Coastal Currents are faster than in the simulation with no meltwater; their mean surface speeds are the highest in the vertical distribution case. In the latter case, there is enhanced baroclinic conversion at the shelf break compared to the simulation with no meltwater. When meltwater is vertically distributed, there is an increase in baroclinic conversion at the shelf break associated with increased eddy kinetic energy. In addition, in the eastern Labrador Sea, the salinity is lower and the meltwater volume is greater when meltwater is vertically distributed. Therefore, the West Greenland Current is sensitive to how meltwater is added to the ocean with implications for the freshening of the Labrador Sea. Significance Statement Our goal is to understand how the flux of freshwater across the West Greenland continental slope into the Labrador Sea is modified by meltwater from the Greenland Ice Sheet. We compare the simulations of the ocean that capture key dynamics along the West Greenland continental slope that have no meltwater, meltwater added to the ocean surface, and meltwater distributed vertically to represent the mixing within fjords. When meltwater is added, the currents along the continental slope are faster, with the greatest increase when meltwater is vertically distributed. In that case, there is enhanced freshening of the Labrador Sea because modified density gradients generate more eddies. Proper representation of the vertical structure of meltwater is important for projecting the impact of freshwater on the subpolar North Atlantic.« less
  4. Influence of open ocean biogeochemistry on aerosol and clouds: Recent findings and perspectives

    Aerosols and clouds are key components of the marine atmosphere, impacting the Earth’s radiative budget with a net cooling effect over the industrial era that counterbalances greenhouse gas warming, yet with an uncertain amplitude. Here we report recent advances in our understanding of how open ocean aerosol sources are modulated by ocean biogeochemistry and how they, in turn, shape cloud coverage and properties. We organize these findings in successive steps from ocean biogeochemical processes to particle formation by nucleation and sea spray emissions, further particle growth by condensation of gases, the potential to act as cloud condensation nuclei or icemore » nucleating particles, and finally, their effects on cloud formation, optical properties, and life cycle. We discuss how these processes may be impacted in a warming climate and the potential for ocean biogeochemistry—climate feedbacks through aerosols and clouds.« less
  5. X-ray absorption spectroscopy and theoretical investigations of the effect of extended ligands in potassium organic matter interaction

    Potassium (K) is an essential nutrient for plant growth, and despite its abundance in soil, most of the K is structurally bound in minerals, limiting its bioavailability and making this soil K reservoir largely inaccessible to plants. Microbial biochemical weathering has been shown to be a promising pathway to sustainably increase plant available K. However, the mechanisms underpinning microbial K uptake, transformation, storage, and sharing are poorly resolved. Here, to better understand the controls on microbial K transformations, we performed K K-edge x-ray absorption near-edge structure (XANES) spectroscopy on K-organic salts, including acetate, citrate, nitrate, oxalate, and tartrate, which aremore » frequently observed as low molecular weight organic acids secreted by soil microbes, as well as humic acid, which acts as a proxy for higher molecular weight organic acids. The organic salts display feature-rich K XANES spectra, each demonstrating numerous unique features spanning ~13 eV range across the absorption edge. In contrast, the spectra for humic acid have one broad, wide feature across the same energy range. We used a combination of time-dependent density functional theory and the Bethe–Salpeter equation based approach within the OCEAN code to simulate the experimental spectra for K-nitrate (KNO3) and K-citrate [K3(C6H5O7)·H2O] to identify the electronic transitions that give rise to some of the outlying and unique spectral features in the organic salts. KNO3 has both the lowest and highest lying energy features, and K3(C6H5O7)·H2O is produced by several soil microbes and is effective at mineral weathering. Our results analyze the K-organic salt bonding in detail to elucidate why the spectral shapes differ and indicate that the K K-edge XANES spectra are associated with the entire ligand despite similar first-shell bonding environments around the K center. The improved understanding of K bonding environments with organic ligands and their use for interpretation of the K-XANES spectra provides an important toolkit to understand how K is transformed by microbial processes and made bioavailable for plant uptake.« less
  6. A New Hybrid Mass-Flux/High-Order Turbulence Closure for Ocean Vertical Mixing

    While various parameterizations of vertical turbulent fluxes at different levels of complexity have been proposed, each has its own limitations. For example, simple first-order closure schemes such as the K-Profile Parameterization (KPP) lack energetic constraints; two-equation models $k-ε$ like directly solve an equation for the turbulent kinetic energy but do not account for non-diffusive fluxes, and high-order closures that include the high-order transport terms are computationally expensive. To address these, we extend the Assumed-Distribution Higher-Order Closure (ADC) framework originally proposed for the atmospheric boundary layer and apply it to the ocean surface boundary layer. By assuming a probability distribution functionmore » relationship between the vertical velocity and tracers, all second-order and higher-order moments are exactly constructed and turbulence closure is achieved in the ADC scheme. In addition, this ADC parameterization has full energetic constraints and includes non-diffusive fluxes without the computational cost of a full higher-order closure scheme. We have tested the ADC scheme against a combination of large eddy simulation (LES), KPP, and $k-ε$ for surface buoyancy-driven convective mixing and found that the ADC scheme is robust with different vertical resolutions and compares well to the LES results.« less
  7. The Global Technical, Economic, and Feasible Potential of Renewable Electricity

    Renewable electricity generation will need to be rapidly scaled to address climate change and other environmental challenges. Doing so effectively will require an understanding of resource availability. We review estimates for renewable electricity of the global technical potential, defined as the amount of electricity that could be produced with current technologies when accounting for geographical and technical limitations as well as conversion efficiencies; economic potential, which also includes cost; and feasible potential, which accounts for societal and environmental constraints. We consider utility-scale and rooftop solar photovoltaics, concentrated solar power, onshore and offshore wind, hydropower, geothermal electricity, and ocean (wave, tidal,more » ocean thermal energy conversion, and salinity gradient energy) technologies. We find that the reported technical potential for each energy resource ranges over several orders of magnitude across and often within technologies. Therefore, we also discuss the main factors explaining why authors find such different results. According to this review and on the basis of the most robust studies, we find that technical potentials for utility-scale solar photovoltaic, concentrated solar power, onshore wind, and offshore wind are above 100 PWh/year. Hydropower, geothermal electricity, and ocean thermal energy conversion have technical potentials above 10 PWh/year. Rooftop solar photovoltaic, wave, and tidal have technical potentials above 1 PWh/year. Salinity gradient has a technical potential above 0.1 PWh/year. The literature assessing the global economic potential of renewables, which considers the cost of each renewable resource, shows that the economic potential is higher than current and near-future electricity demand. Fewer studies have calculated the global feasible potential, which considers societal and environmental constraints. While these ranges are useful for assessing the magnitude of available energy sources, they may omit challenges for large-scale renewable portfolios.« less
  8. Continuous observations of the surface energy budget and meteorology over the Arctic sea ice during MOSAiC

    Abstract The Multidisciplinary drifting Observatory for the Study of Arctic Climate (MOSAiC) was a yearlong expedition supported by the icebreaker R/V Polarstern , following the Transpolar Drift from October 2019 to October 2020. The campaign documented an annual cycle of physical, biological, and chemical processes impacting the atmosphere-ice-ocean system. Of central importance were measurements of the thermodynamic and dynamic evolution of the sea ice. A multi-agency international team led by the University of Colorado/CIRES and NOAA-PSL observed meteorology and surface-atmosphere energy exchanges, including radiation; turbulent momentum flux; turbulent latent and sensible heat flux; and snow conductive flux. There were fourmore » stations on the ice, a 10 m micrometeorological tower paired with a 23/30 m mast and radiation station and three autonomous Atmospheric Surface Flux Stations. Collectively, the four stations acquired ~928 days of data. This manuscript documents the acquisition and post-processing of those measurements and provides a guide for researchers to access and use the data products.« less
  9. Arctic ice-ocean interactions in an 8-to-2 kilometer resolution global model

    In the last decades, the Arctic climate has changed dramatically, with the loss of multiyear sea ice one of the clearest consequences. These changes have occurred on relatively rapid timescales, and both accurate short-term Arctic prediction (e.g., 10 days to three months) and climate projection of future Arctic scenarios present ongoing challenges. Here we describe a representation of the Arctic ocean and sea ice in a ultrahigh resolution simulation in which the horizontal grid mesh reduces from 8 km at the equator to 2 km at the poles (UH8to2) for the years 2017-2020. We find the simulation reproduces observed distributionsmore » of seasonal sea-ice thickness and concentration realistically, although concentration is biased low in the spring and summer and low biases in thickness are found in the central and eastern basins in the fall. Volume, fresh water, and heat transports through key passages are realistic, lying within observationally determined ranges. Climatological comparisons reveal that the UH8to2 Atlantic Water is shallower, warmer, and saltier than the World Ocean Atlas 2018 climatology for 2005-2017 in the eastern basin. Our analysis suggests that these biases, combined with a lack of stratification in the upper 100 m of the simulated ocean, contribute to the winter biases in modeled sea ice thickness. This relationship between biases in the sea ice and ocean points to a potential positive feedback within the model, illuminating challenges for long term model predictive power in a changing Arctic climate.« less
  10. Non-Synchronous Rotation on Europa Driven by Ocean Currents

    It has been suggested that the ice shell of Jupiter's moon Europa may drift non-synchronously due to tidal torques. Here we argue that torques applied by the underlying ocean are also important and can result in non-synchronous rotation. The resulting spin rate can be slightly slower than the synchronous angular rate that would have kept the same point of the ice shell facing Jupiter. We develop an ice shell rotation model, driven by ocean stress calculated using a high-resolution state-of-the-art ocean general circulation model, and take into account the viscoelastic deformation of the ice shell. We use the ice shellmore » model results together with observed limits on the ice shell drift speed to constrain ice shell parameters such as effective viscosity, which is currently uncertain by at least four orders of magnitude. Our results suggest, at best, sluggish ice shell convection. Depending on the relaxation time scale of the ice shell and on the ocean currents, the ice shell may exhibit negligible drift, constant drift, or oscillatory drift superimposed on random fluctuations. The expected rotation rate exceeds ~30 m/yr; future spacecraft observations can be used to test these predictions and yield insight into the properties of the ice shell and underlying ocean.« less
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